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Question

Chemistry Question on Qualitative Analysis

Consider the following test for a group-IV cation. M2++H2SA (Black precipitate)+byproduct\text{M}^{2+} + \text{H}_2\text{S} \rightarrow \text{A (Black precipitate)} + \text{byproduct} A + aqua regiaB + NOCl + S + H2O\text{A + aqua regia} \rightarrow \text{B + NOCl + S + H}_2\text{O} B + KNO2+CH3COOHC + byproduct\text{B + KNO}_2 + \text{CH}_3\text{COOH} \rightarrow \text{C + byproduct} The spin-only magnetic moment value of the metal complex C\text{C} is \dots \dots \dots BM. (Nearest integer)

Answer

From the reactions, the metal complex formed is likely in the 4+^+ oxidation state, which leads to no unpaired electrons. For such complexes, the spin-only magnetic moment is zero because all electrons are paired. Hence, the magnetic moment is:
μ=0BM\mu = 0 { BM}
Thus, the correct answer is (0).

Explanation

Solution

From the reactions, the metal complex formed is likely in the 4+^+ oxidation state, which leads to no unpaired electrons. For such complexes, the spin-only magnetic moment is zero because all electrons are paired. Hence, the magnetic moment is:
μ=0BM\mu = 0 { BM}
Thus, the correct answer is (0).