Question
Question: Consider a reaction A<sub>(g)</sub>¾® 3 B<sub>(g)</sub> + 2C<sub>(g)</sub> with rate constant 1.386 ...
Consider a reaction A(g)¾® 3 B(g) + 2C(g) with rate constant 1.386 × 10–2 min–1. Starting with 2 moles of A in 12.5 litre vessel, if reaction is allowed to takes place at constant pressure & at 298 K then find the concentration of B after 100 min -
A
0.04M
B
0.36 M
C
0.09
D
None of these
Answer
0.09
Explanation
Solution
K = t1/20.693 or t1/2 = 1.38×10–20.693 = 50 min
A(g) ¾® 3B(g) + 2C(g)
after 2 – x 3x 2x
100 min = 0.5 4.5 3
ViVf = ninf Ž Vf = 28 × 12.5 Ž 50 Lit
\ Concentration of B after
100 min = 504.5 = 0.09 M