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Question

Chemistry Question on The solid state

Conductivity of silicon increases by doping it with group-15 elements. Doping means introduction of small amount of impurities like P,AsP, As or BiBi into the pure crystal.

A

If both assertion and reason are true and reason is the correct explanation of assertion

B

If both assertion and reason are true but reason is not the correct explanation of assertion

C

If assertion is true but reason is false

D

If both assertion and reason are false

Answer

If both assertion and reason are true but reason is not the correct explanation of assertion

Explanation

Solution

When a silicon crystal is doped with a group-15 elements, such as P,As,SbP, A s, S b or BiB i the structure of the crystal lattice is left unchanged but an occasional atom with five valence electrons occupies a site that would normally be occupied by a silicon atom. The foreign atom uses four of its electrons in covalent bonding but the remaining fifth electron becomes delocalised and is thus free to contribute to electrical conduction.