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Question: Compound A reacts with ![](https://cdn.pureessence.tech/canvas_317.png?top_left_x=1361&top_left_y=16...

Compound A reacts with to give B which on treatment with KCN followed by hydrolysis gave propionic acid. What is A and B respectively

A

and

B

C2H6\mathrm { C } _ { 2 } \mathrm { H } _ { 6 } and C2H5Cl\mathrm { C } _ { 2 } \mathrm { H } _ { 5 } \mathrm { Cl }

C

C2H5Cl\mathrm { C } _ { 2 } \mathrm { H } _ { 5 } \mathrm { Cl }andC2H5Cl\mathrm { C } _ { 2 } \mathrm { H } _ { 5 } \mathrm { Cl }

D

C2H5Cl\mathrm { C } _ { 2 } \mathrm { H } _ { 5 } \mathrm { Cl }

Answer

C2H5Cl\mathrm { C } _ { 2 } \mathrm { H } _ { 5 } \mathrm { Cl }

Explanation

Solution

C2H5OH+PCl5 (A) C2H5Cl+POCl3 (B) +HCl\underset { \text { (A) } } { \mathrm { C } _ { 2 } \mathrm { H } _ { 5 } \mathrm { OH } + \mathrm { PCl } _ { 5 } } \rightarrow \underset { \text { (B) } } { \mathrm { C } _ { 2 } \mathrm { H } _ { 5 } \mathrm { Cl } + \mathrm { POCl } _ { 3 } } + \mathrm { HCl }

C2H5Cl+KCNC2H5CN+KCl\mathrm { C } _ { 2 } \mathrm { H } _ { 5 } \mathrm { Cl } + \mathrm { KCN } \rightarrow \mathrm { C } _ { 2 } \mathrm { H } _ { 5 } \mathrm { CN } + \mathrm { KCl } (B)