Question
Question: Complete the following table of displacement reaction. Identify oxidising and reducing agents involv...
Complete the following table of displacement reaction. Identify oxidising and reducing agents involved.
Reactants | Products |
---|---|
1. Zn\left( S \right) + \,\\_\\_\\_\\_\\_\left( {aq} \right) | \\_\\_\\_\\_\\_\left( {aq} \right) + Cu\left( S \right) |
2. Cu(S)+2Ag+(aq) | \\_\\_\\_\\_ + \\_\\_\\_\\_ |
Solution
Hint : When the ions of a metal higher in the electrochemical series are combined with the ions of a metal lower in the electrochemical series, displacement reactions occur. The more reactive metal's atoms force their electrons onto the less reactive metal's ions.
Complete Step By Step Answer:
Reduction and oxidation (redox) reactions are chemical reactions that involve the exchange of electrons. When a chemical species loses electrons, it is said to be oxidised, and when it receives electrons, it is said to be reduced.
Now, coming to the question:
1. Zn\left( S \right) + \,\\_\\_\\_\\_\\_\left( {aq} \right) \to \\_\\_\\_\\_\left( {aq} \right) + Cu\left( S \right)
In this reaction because zinc has a higher reactivity than copper, it replaces copper in a copper sulphate (CuSO4) solution and creates zinc sulphate. The colour of the solution changes from blue to colourless during the operation.
The chemical equation of the reaction;
Zn + CuSO4→ ZnSO4+ Cu
So, in this displacement reaction Copper sulphate (CuSO4) acts as an oxidising agent by supplying oxygen to zinc, whereas zinc acts as a reducing agent by absorbing oxygen.
2. Cu\left( S \right) + 2A{g^ + }\left( {aq} \right) \to \\_\\_\\_\\_ + \\_\\_\\_\\_
In solution, copper metal became copper ions, while silver ions created silver metal.
Cu(s) + 2Ag+(aq)→Cu2+(aq) + 2Ag(s)
Cu(s) ions lose electrons to become Cu2+(aq) ions, while Ag+(aq) ions gain electrons to become Ag+(aq) ions . The Cu(s) loses electrons to be oxidized to Cu2+(aq) . The Ag+(aq) gain electrons to be reduced to Ag(s).
Note :
If the standard electrode potential for the redox reaction , E0(Redoxreaction) , is positive, the redox reaction is spontaneous. The reaction will move forward if , E0(Redoxreaction) is positive (spontaneous). We wouldn't anticipate the reverse reaction to be spontaneous after observing the spontaneous reaction of Ag+and Cu . As a result, there is no interaction between Ag metal andCu2+.