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Question: Complete the following chemical reaction equation: (i)\(P{{H}_{3}}+HgC{{l}_{2}}\to \) (ii) \(PC...

Complete the following chemical reaction equation:
(i)PH3+HgCl2P{{H}_{3}}+HgC{{l}_{2}}\to
(ii) PCl3+H2O(excess)PC{{l}_{3}}+{{H}_{2}}O(excess)\to

Explanation

Solution

The chemical PH3P{{H}_{3}} is called phosphine and it is weakly basic in nature. The compound HgCl2HgC{{l}_{2}} is called mercuric chloride. Generally phosphine chemical is going to absorb on the surface of the metallic derivatives and forms M3P2{{M}_{3}}{{P}_{2}} compound as the product.

Complete answer:
- In the question it is asked to complete the given chemical reactions.
- The first given chemical reaction is as follows.
PH3+HgCl2P{{H}_{3}}+HgC{{l}_{2}}\to
- We know that phosphine is going to form a compound by reacting with copper sulphate and forms a product like Cu3P2C{{u}_{3}}{{P}_{2}} .
- The chemical reaction of phosphine with copper sulphate is as follows.
2PH3+3CuSO4Cu3P2+3H2SO42P{{H}_{3}}+3CuS{{O}_{4}}\to C{{u}_{3}}{{P}_{2}}+3{{H}_{2}}S{{O}_{4}}
- Now we can complete the given chemical reaction by taking the above chemical reaction as an example.
2PH3+3HgCl2Hg3P2Mercuric phosphide+6HCl2P{{H}_{3}}+3HgC{{l}_{2}}\to \underset{Mercuric\text{ }phosphide}{\mathop{H{{g}_{3}}{{P}_{2}}}}\,+6HCl
- In the above chemical reaction two moles of phosphine is going to react with 3 moles of mercuric chloride and forms one moles of mercuric phosphide and 6 moles of hydrochloric acid as the products.
- Coming to the given second chemical reaction.
PCl3+H2O(excess)PC{{l}_{3}}+{{H}_{2}}O(excess)\to
- We know that phosphorus trichloride reacts with water and forms phosphorous acid as the product.
- The chemical reaction of phosphorus trichloride with water is as follows.
PCl3+3H2OH3PO3+3HClPC{{l}_{3}}+3{{H}_{2}}O\to {{H}_{3}}P{{O}_{3}}+3HCl
- In the above chemical reaction one mole of phosphorus trichloride with 3 moles of water forms phosphorus acid and 3 moles of hydrochloric acid as the products.

Note:
In both the chemical reaction phosphorus derivative is going to react different chemicals and finally after the completion of the chemical reaction acids are commonly formed in both the Chemical reactions.