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Question

Chemistry Question on Organic Chemistry- Some Basic Principles and Techniques

Complete combustion of 1.80g1.80 g of an oxygen containing compound (CxHyO2)\left( C _{ x } H _{ y } O _{2}\right) gave 2.64g2.64 g of CO2CO _{2} and 1.08g1.08 g of H2OH _{2} O. The percentage of oxygen in the organic compound is:

A

51.63

B

63.53

C

53.33

D

50.33

Answer

53.33

Explanation

Solution

The correct answer is (C) : 53.33
nc=nco2=2.6444=0.06n _{ c }= n _{ co _{2}}=\frac{2.64}{44}=0.06
nH=2×nH2O=1.0818×2=0.12n _{ H }=2 \times n _{ H _{2} O }=\frac{1.08}{18} \times 2=0.12
m0=1.8012×2.64441.0818×2m _{0}=1.80-12 \times \frac{2.64}{44}-\frac{1.08}{18} \times 2
=1.800.720.12=0.96gm\quad=1.80-0.72-0.12=0.96 gm
%0=0.961.80×100=53.33%\% 0=\frac{0.96}{1.80} \times 100=53.33 \%