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Question: Complete and balance the following chemical equations: (a) \(Zn(s)+HCl(aq)\to \) (b) \(N{{a}_{2...

Complete and balance the following chemical equations:
(a) Zn(s)+HCl(aq)Zn(s)+HCl(aq)\to
(b) Na2CO3(s)+2HCl(aq)N{{a}_{2}}C{{O}_{3}}(s)+2HCl(aq)\to
(c) NaHCO3(s)+HCl(aq)NaHC{{O}_{3}}(s)+HCl(aq)\to
(d) NaOH(aq)+HCl(aq)NaOH(aq)+HCl(aq)\to
(e) CuO(s)+HCl(aq)CuO(s)+HCl(aq)\to

Explanation

Solution

The addition of stoichiometric coefficients to the reactant and products involves balancing chemical equations. The law of conservation must be followed by chemical equations and the law of constant proportions is very important in balancing chemical equations. The traditional balancing method and the algebraic balancing method are the two quick easy methods of balancing a chemical equation.

Complete step by step solution:
The arrowhead points show the direction of products in the reaction.
A chemical equation represents a chemical reaction when chemical formulas are used instead of words. Balancing the given chemical equation using traditional balancing method:
Step-1: first complete the given equations with products
(a) Zn(s)+HCl(aq)ZnCl2(aq)+H2(g)Zn(s)+HCl(aq)\to ZnC{{l}_{2}}(aq)+{{H}_{2}}(g)
(b) Na2CO3(s)+2HCl(aq)NaCl(aq)+H2O(l)+CO2(g)N{{a}_{2}}C{{O}_{3}}(s)+2HCl(aq)\to NaCl(aq)+{{H}_{2}}O(l)+C{{O}_{2}}(g)
(c) NaHCO3(s)+HCl(aq)NaCl(aq)+CO2(g)+H2O(l)NaHC{{O}_{3}}(s)+HCl(aq)\to NaCl(aq)+C{{O}_{2}}(g)+{{H}_{2}}O(l)
(d) NaOH(aq)+HCl(aq)NaCl(aq)+H2O(l)NaOH(aq)+HCl(aq)\to NaCl(aq)+{{H}_{2}}O(l)
(e) CuO(s)+HCl(aq)CuCl2(aq)+H2O(l)CuO(s)+HCl(aq)\to CuC{{l}_{2}}(aq)+{{H}_{2}}O(l)
Step-2: Count and compare the number of atoms of each element on LHS and RHS of the arrow. Check the number of atoms of each element is the same on both sides of the reaction, then the equation is said to be unbalanced. Because both sides of the chemical equation, the mass is not the same.

(a) Chemical equation: Zn(s)+HCl(aq)ZnCl2(aq)+H2(g)Zn(s)+HCl(aq)\to ZnC{{l}_{2}}(aq)+{{H}_{2}}(g)

Reactants side| Product side
One Zn from Zn(s)| One Zn from Zn(s)
One hydrogen atom from HCl(aq)| two hydrogen atoms from H2(g){{H}_{2}}(g)
One Chlorine atom from HCl (aq)| Two Chlorine atom from ZnCl2(aq)ZnC{{l}_{2}}(aq)
(b) Chemical equation: Na2CO3(s)+2HCl(aq)NaCl(aq)+H2O(l)+CO2(g)N{{a}_{2}}C{{O}_{3}}(s)+2HCl(aq)\to NaCl(aq)+{{H}_{2}}O(l)+C{{O}_{2}}(g)
Reactants side| Product side
Two sodium atoms from Na2CO3N{{a}_{2}}C{{O}_{3}} | One Na atom from NaCl
One C atom from Na2CO3N{{a}_{2}}C{{O}_{3}}| One C atom from CO2C{{O}_{2}}
three O atoms from Na2CO3N{{a}_{2}}C{{O}_{3}}| one O atom from H2O{{H}_{2}}O and two O atoms from CO2C{{O}_{2}}
Two hydrogen atoms from HCl| Two hydrogen atoms from H2O{{H}_{2}}O
(c) Chemical equation: NaHCO3(s)+HCl(aq)NaCl(aq)+CO2(g)+H2O(l)NaHC{{O}_{3}}(s)+HCl(aq)\to NaCl(aq)+C{{O}_{2}}(g)+{{H}_{2}}O(l)
Reactants side| Product side
one sodium atom from NaHCO3NaHC{{O}_{3}} | One Na atom from NaCl
One C atom from NaHCO3NaHC{{O}_{3}}| One C atom from CO2C{{O}_{2}}
three O atoms from NaHCO3NaHC{{O}_{3}}| one O atom from H2O{{H}_{2}}O and two O atoms from CO2C{{O}_{2}}
Two hydrogen atoms from HCl and NaHCO3NaHC{{O}_{3}} | Two hydrogen atoms from H2O{{H}_{2}}O
(d) Chemical equation: NaOH(aq)+HCl(aq)NaCl(aq)+H2O(l)NaOH(aq)+HCl(aq)\to NaCl(aq)+{{H}_{2}}O(l)
Reactants side| Product side
one sodium atom from NaOH| One Na atom from NaCl
One Cl atom from HCl| One Cl atom from NaCl
One O atom from NaOH| one O atom from H2O{{H}_{2}}O
Two hydrogen atoms from HCl and NaOH| Two hydrogen atoms from H2O{{H}_{2}}O
(e) Chemical equation: CuO(s)+HCl(aq)CuCl2(aq)+H2O(l)CuO(s)+HCl(aq)\to CuC{{l}_{2}}(aq)+{{H}_{2}}O(l)
Reactants side| Product side
one Cu atom from CuO| One Cu atom from CuCl2CuC{{l}_{2}}
One Cl atom from HCl| Two Cl atoms from CuCl2CuC{{l}_{2}}
One O atom from CuO| one O atom from H2O{{H}_{2}}O
One hydrogen atom from HCl | Two hydrogen atoms from H2O{{H}_{2}}O

Step: 3 Recollect once, the law of conservation of mass states that mass can neither be created nor destroyed in a chemical reaction, which means the total mass of the elements present in the products of the chemical reaction has to be equal to the total mass of the elements present in the reactants.

(a) Chemical equation: Zn(s)+2HCl(aq)ZnCl2(aq)+H2(g)Zn(s)+2HCl(aq)\to ZnC{{l}_{2}}(aq)+{{H}_{2}}(g)

Reactants side| Product side
One Zn from Zn(s)| One Zn from Zn(s)
two hydrogen atoms from HCl(aq)| two hydrogen atoms from H2(g){{H}_{2}}(g)
two Chlorine atom from HCl (aq)| Two Chlorine atom from ZnCl2(aq)ZnC{{l}_{2}}(aq)
(b) Chemical equation: Na2CO3(s)+2HCl(aq)2NaCl(aq)+H2O(l)+CO2(g)N{{a}_{2}}C{{O}_{3}}(s)+2HCl(aq)\to 2NaCl(aq)+{{H}_{2}}O(l)+C{{O}_{2}}(g)
Reactants side| Product side
Two sodium atoms from Na2CO3N{{a}_{2}}C{{O}_{3}} | two Na atoms from NaCl
One C atom from Na2CO3N{{a}_{2}}C{{O}_{3}}| One C atom from CO2C{{O}_{2}}
three O atoms from Na2CO3N{{a}_{2}}C{{O}_{3}}| one O atom from H2O{{H}_{2}}O and two O atoms from CO2C{{O}_{2}}
Two hydrogen atoms from HCl| Two hydrogen atoms from H2O{{H}_{2}}O
(c) Chemical equation: NaHCO3(s)+HCl(aq)NaCl(aq)+CO2(g)+H2O(l)NaHC{{O}_{3}}(s)+HCl(aq)\to NaCl(aq)+C{{O}_{2}}(g)+{{H}_{2}}O(l)
Reactants side| Product side
one sodium atom from NaHCO3NaHC{{O}_{3}} | One Na atom from NaCl
One C atom from NaHCO3NaHC{{O}_{3}}| One C atom from CO2C{{O}_{2}}
three O atoms from NaHCO3NaHC{{O}_{3}}| one O atom from H2O{{H}_{2}}O and two O atoms from CO2C{{O}_{2}}
Two hydrogen atoms from HCl and NaHCO3NaHC{{O}_{3}} | Two hydrogen atoms from H2O{{H}_{2}}O
(d) Chemical equation: NaOH(aq)+HCl(aq)NaCl(aq)+H2O(l)NaOH(aq)+HCl(aq)\to NaCl(aq)+{{H}_{2}}O(l)
Reactants side| Product side
one sodium atom from NaOH| One Na atom from NaCl
One Cl atom from HCl| One Cl atom from NaCl
One O atom from NaOH| one O atom from H2O{{H}_{2}}O
Two hydrogen atoms from HCl and NaOH| Two hydrogen atoms from H2O{{H}_{2}}O
(e) Chemical equation: CuO(s)+2HCl(aq)CuCl2(aq)+H2O(l)CuO(s)+2HCl(aq)\to CuC{{l}_{2}}(aq)+{{H}_{2}}O(l)
Reactants side| Product side
one Cu atom from CuO| One Cu atom from CuCl2CuC{{l}_{2}}
Two Cl atoms from HCl| Two Cl atoms from CuCl2CuC{{l}_{2}}
One O atom from CuO| one O atom from H2O{{H}_{2}}O
Two hydrogen atoms from HCl | Two hydrogen atoms from H2O{{H}_{2}}O

Hence, the complete and balanced equations are
(a) Zn(s)+2HCl(aq)ZnCl2(aq)+H2(g)Zn(s)+2HCl(aq)\to ZnC{{l}_{2}}(aq)+{{H}_{2}}(g)
(b) Na2CO3(s)+2HCl(aq)2NaCl(aq)+H2O(l)+CO2(g)N{{a}_{2}}C{{O}_{3}}(s)+2HCl(aq)\to 2NaCl(aq)+{{H}_{2}}O(l)+C{{O}_{2}}(g)
(c) NaHCO3(s)+HCl(aq)NaCl(aq)+CO2(g)+H2O(l)NaHC{{O}_{3}}(s)+HCl(aq)\to NaCl(aq)+C{{O}_{2}}(g)+{{H}_{2}}O(l)
(d) NaOH(aq)+HCl(aq)NaCl(aq)+H2O(l)NaOH(aq)+HCl(aq)\to NaCl(aq)+{{H}_{2}}O(l)
(e) CuO(s)+2HCl(aq)CuCl2(aq)+H2O(l)CuO(s)+2HCl(aq)\to CuC{{l}_{2}}(aq)+{{H}_{2}}O(l)

Note: For example, when milk is left at room temperature or food is cooked, or food gets digestion in our body. In these situations, the nature and identity of the initial substance had changed. Whenever a chemical change takes place, that chemical reaction represents the change in a reaction.