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Question

Chemistry Question on coordination compounds

[Co(NH3)6]3+is[Co(NH_3)_6]^{3+} \text{is} hybridised and\text{hybridised and}

A

d2sp3d^2sp^3, Diamagnetic

B

d2sp3d^2sp^3, Paramagnetic

C

sp3d2sp^3d^2, Diamagnetic

D

sp3d2sp^3d^2, Paramagnetic

Answer

sp3d2sp^3d^2, Diamagnetic

Explanation

Solution

The correct option is (c ): sp3d2and Diamagneticsp^3d^2\text{and Diamagnetic}
In [Co (NH3)6]3+, Co is in +3 oxidation state with the configuration 3d6. In the presence of NH3 a strong ligand, the 3d electrons pair up leaving two d-orbitals empty.
Hence, the hybridization is sp3d2 forming an inner orbital octahedral complex.