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Question

Chemistry Question on coordination compounds

[Co(NH3)5Br)]SO4[Co(NH_3)_5Br)] \,SO_4 and [Co(NH3)5SO4]Br[Co(NH_3)_5SO_4] \,Br are examples of which type of isomerism ?

A

Linkage

B

Geometrical

C

Ionisation

D

Optical

Answer

Ionisation

Explanation

Solution

[Co(NH3)5Br]SO4 [Co(NH_3)_5Br]SO_4 and [Co(NH3)5SO4]Br[Co(NH_3)_5SO_4] Br are examples of ionisation isomerism. This form of isomerism arises when the counter ion in a complex salt is itself a potential ligand and can displace a ligand which can then become the counter ion.