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Question

Chemistry Question on Haloalkanes and Haloarenes

Chloromethane on treatment with excess of ammonia yields mainly

A

B

NN-methylmethanamine (CH3??H??H3)(CH_3??H??H_3)

C

methanamine (CH3NH2)(CH_3NH_2)

D

mixture containing all these in equal proportion

Answer

methanamine (CH3NH2)(CH_3NH_2)

Explanation

Solution

CH3ClChloromethane+\underset{\text{Chloromethane}}{ {CH3Cl}} + NH3(excess)>\underset{\text{(excess)}}{ {NH3}} {->} CH3NH2Methanamine+HCl\underset{\text{Methanamine}}{ {CH3NH2}} {+ HCl} Primary amine is obtained as a major product by taking large excess of ammonia.