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Question: Chlorine is prepared in the laboratory by treating manganese dioxide \[\left( {Mn{O_2}} \right)\] wi...

Chlorine is prepared in the laboratory by treating manganese dioxide (MnO2)\left( {Mn{O_2}} \right) with aqueous hydrochloric acid according to reaction.
MnO2 + 4HCl MnCl2+Cl2+2H2OMnO2{\text{ }} + {\text{ }}4HCl \to {\text{ }}MnCl2 + Cl2 + 2H2O
How many grams of HClHClwill react with 5 gm. ofMnO2Mn{O_2}?

Explanation

Solution

Hint-We have to determine the number of moles ofHClHCl required completing the reaction. We can use the values of the number of moles to determine the mass of the compound.

Complete step by step answer:
From the given chemical equation of the reaction is
MnO2 + 4HCl MnCl2+Cl2+2H2OMnO2{\text{ }} + {\text{ }}4HCl \to {\text{ }}MnCl2 + Cl2 + 2H2O
So, in this reaction we can understand that the 1 mole of MnO2Mn{O_2} reacts with 4 moles of HClHCl
Now,
Mass of MnO2Mn{O_2} = atomic mass of Manganese + 2(atomic mass of oxygen)
Therefore, we can write the mass of MnO2Mn{O_2} is =55 +2(16)55{\text{ }} + 2\left( {16} \right)
= 87 gms/mole= {\text{ }}87{\text{ }}gms/mole
This means, 1 mole of MnO2Mn{O_2} comprises 87 gm of MnO2.
Similarly,
Mass of HClHCl = atomic mass of Hydrogen + atomic mass of Chlorine
Therefore, we can write as mass of HClHCl = 1 + 35.451{\text{ }} + {\text{ }}35.45
=36.46 gms/mole= 36.46{\text{ }}gms/mole
This means, 1 mole of HClHCl comprises a mass of 36.46 gm of MnO2.
So, 4 moles of HClHCl = 4 ×36.46 gm. = 145.84 gm of HClHCl
Thus, according to given chemical equation,
145.84 gm. of HClHCl reacts with 87 gm. of MnO2Mn{O_2} to accomplish the reaction.
So now we can find the mass of HClHCl reacts with 5gm of MnO2Mn{O_2} to accomplish the reaction.
\therefore Mass of HClHCl (gm.) required = 145.84×587=\dfrac{{145.84 \times 5}}{{87}} = 8.38 gm.
Hence, the answer is, 8.38 gm. of HClHCl will require to react with 5 gm. of MnO2Mn{O_2}

Note: We should have knowledge of atomic masses of the elements in order to calculate the mass of compounds in the given chemical reaction and also about the calculating number of moles based on the chemical equation given.