Question
Question: Chemical reaction of aldehydes and ketones....
Chemical reaction of aldehydes and ketones.
Solution
Both the aldehyde and ketone group has carbonyl group, i.e., >C=O group and they give many chemical reactions like Nucleophilic addition reaction, reduction reaction, oxidation reaction, halogenations, and reaction with alkalis.
Complete answer:
Some chemical reaction of aldehydes and ketones are:
(i)- Addition of hydrogen cyanide:
Acetaldehyde in reaction with hydrogen cyanide gives acetaldehyde cyanohydrins. The reaction is:
Acetone in reaction with hydrogen cyanide gives acetone cyanohydrins. The reaction is:
(ii)- Addition of Grignard reagent:
Formaldehyde when reacted with Grignard reagent produces primary alcohol. The reaction is given below:
Acetaldehyde when reacts with Grignard reagent, it produces secondary alcohol. The reaction is given below:
Acetone when reacts with Grignard reagent, it produces tertiary alcohol. The reaction is given below:
(iii)- Addition of ammonia derivative:
Aldehyde or ketone when reacted with ammonia derivatives forms a group containing −C=N− group.
(iv)- Reduction reaction:
Aldehydes or ketones on reduction gives respective alcohols in the presence of platinum or palladium and their reactions are given below:
RCHO→RCH2OH
>C=O→>CHOH
The reduction can be done by many catalysts like zinc-amalgam, hydrazine and potassium hydroxide, and hydriodic acid, and red phosphorus.
(v)- Oxidation reaction:
Aldehydes and ketones on oxidation form respective carboxylic acids. The reactions are given below:
(vi)- Halogenation reaction:
Aldehydes and ketones also give halogenations reaction as given below:
(vii)- Reaction with alkalis:
Aldehydes and ketones in the presence of dilute sodium hydroxide give aldols. These reactions are given below:
Note:
The reaction of aldehydes and ketones with alkalies is known as an aldol condensation reaction. Aldehydes and ketones show so many chemical reactions because they are very reactive.