Question
Question: CH3MgCl+SnCl4...
CH3MgCl+SnCl4
Tetramethyltin ((CH3)4Sn)
Solution
The reaction between methylmagnesium chloride (CH3MgCl), a Grignard reagent, and tin(IV) chloride (SnCl4) is an alkylation reaction. The methyl group from the Grignard reagent acts as a nucleophile, attacking the electrophilic tin center in SnCl4. All four chlorine atoms on the tin can be replaced by methyl groups.
The overall balanced chemical equation for the reaction is:
4 CH3MgCl+SnCl4→(CH3)4Sn+4 MgCl2
The main product formed is tetramethyltin, (CH3)4Sn. Magnesium chloride (MgCl2) is formed as a byproduct.
Explanation:
Methylmagnesium chloride provides methyl anions (CH3− equivalents) which are strong nucleophiles. Tin(IV) chloride has an electrophilic tin atom. The methyl groups replace the chlorine atoms on tin in a stepwise manner, ultimately leading to the formation of tetramethyltin when sufficient Grignard reagent is present.