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Question

Chemistry Question on Alcohols, Phenols and Ethers

CH3CH2OHCH_3CH_2OH can be converted into CH3CHOCH_3CHO by

A

catalytic hydrogenation

B

treatment with LiAlH4LiAlH_4

C

treatment with pyridinium chlorochromate

D

treatment with KMnO4KMnO_4

Answer

treatment with pyridinium chlorochromate

Explanation

Solution

Pyridinium chlorochromate (PCC)(PCC), a complex of chromium trioxide with pyridine and HClHCl gives good yield of aldehydes and prevents further oxidation to carboxylic acids. CH3CH2OH>[PCC]CH3CHO {CH_3CH_2OH ->[PCC] CH3CHO}