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Question

Chemistry Question on Alkanes

CH3CH2BrCH_3CH_2Br undergoes Wurtz reaction. We may expect some of the following product A:CH3CH2CH2CH3A : CH_3CH_2CH_2CH_3 B:CH2=CH2B : CH_2 = CH_2 C:CH3?CH3C : CH_3 ? CH_3 Select correct product.

A

Only A

B

A and B

C

A, B and C

D

A and C

Answer

A, B and C

Explanation

Solution

C2H5Br+Na?CH3CH2?+NaBrC_{2}H_{5}Br + Na^{?} \to CH_{3} CH_{2}^{?} + NaBr
Intermediate free radical CH3CH2?CH_{3} CH_{2}^{?} combines to form CH3CH2CH2CH3CH_{3}CH_{2} - CH_{2}CH_{3} (as amain product) and also CH2==CH2CH_{2} == CH_{2} and CH3CH3C H_{3}CH_{3} by disproportion