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Question: Cerium (Z = 58) is an important member of the lanthanoide. Which of the following statement about ce...

Cerium (Z = 58) is an important member of the lanthanoide. Which of the following statement about cerium is incorrect?

A

The common oxidation state of cerium are +3 and +4.

B

The +3 oxidation state of cerium is more stable than +4 oxidation state.

C

The +4 oxidation state of cerium is not known in solution.

D

Cerium (IV) acts as an oxidizing agent.

Answer

The +4 oxidation state of cerium is not known in solution.

Explanation

Solution

(3) Cerium can also show the oxidation state of +4 in solution as it leads to a noble gas configuration, from [Xe]54 4f1 5d1 6s2 to [Xe]54, after losing four electrons. It is only Ce4+ which exist in solution among the lanthanides.