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Question

Chemistry Question on Thermodynamics

Cell reaction is spontaneous when

A

Ered0E^0_{red} is negative

B

Ered0E^0_{red} is positive

C

ΔG0ΔG^0 is negative

D

ΔG0ΔG^0 is positive

Answer

ΔG0ΔG^0 is negative

Explanation

Solution

When the value of ΔG0ΔG^0 is negative, the cell reaction is spontaneous.
ΔG0=nFE0\, \, \, \, \, \, \, \, \, \, \, \, ΔG^0=-nFE^0
where, n = number of electrons take part
F = Faraday constant E0=E^0= EMF of the cell
Thus, for a spontaneous reaction, the EMF of the cell must be positive.