Question
Question: Calculate the volume of air containing \(21\% \) by volume of oxygen at NTP required to convert \(29...
Calculate the volume of air containing 21% by volume of oxygen at NTP required to convert 294cm3 of SO2 into SO3 under the same condition.
A) 200ml
B) 300ml
C) 500ml
D) 700ml
Solution
We have to know that the standard temperature and pressing factor are standard arrangements of conditions for trial estimations to be set up to permit correlations to be made between various arrangements of information. The most utilized norms are those of the International Union of Pure and Applied Chemistry (IUPAC) and the National Institute of Standards and Technology (NIST), albeit these are not all around acknowledged guidelines. Different associations have set up an assortment of elective definitions for their standard reference conditions.
Complete answer:
The condition of the response of sulfur dioxide and Oxygen to give sulfur trioxide, is given beneath:
2SO2(g)+O2(g)→SO3(g)
We can ascertain the moles of SO2 and use it to discover the moles of O2 needed by utilizing the condition.
We have 294cm3 of SO2 . We can ascertain the moles of the SO2 by utilization of Avogadro’s law.
Avagardo law expresses that 1 mole of any gas possesses precisely 22.4L by volume at STP.
Having this as a main priority, let us convert 22.4 to liters.
1000cm3=1L
At that point,
294cm3=1000294cm3=0.294L
Convert 0.294L to moles:
On the off chance that 22.4L=1mole
At that point,
0.294L=22.41 mole×0.294=0.013125moles
Utilize the mole proportion in the condition to discover the moles of the oxygen required:
Mole proportion of Sulfur dioxide is 2:1
Hence the moles of the oxygen utilized is
2moles0.013125=0.0065625moles
This is the quantity of moles of oxygen from the condition:
We will utilize a similar Avogadro’s law to discover the volume of oxygen from the moles
In the event that one mole involves 22.4L
At that point 0.0065625 moles will involve,
1mole0.0065625moles×22.4=0.147Liter
The measure of oxygen spent in this response is 0.147 liters or147cm3.
The subsequent stage is to ascertain the measure of air that contains 147cm3 of oxygen
On the off chance that 21%=147cm3
At that point,
100%=21147×100=700cm3
Hence the volume of air required is 700cm3.
Thus option D is correct.
Note:
We realize that, one mole of gas possesses 22.4L at NTP one mole of O2 gas involves 22.4Lat NTP O2 contains two moles of oxygen particle. Subsequently two moles of oxygen atom possesses 22.4L at NTP,
Mole=22.4Volume
Therefore, one mole of an oxygen molecule contains 222.4=11.2L at NTP.