Question
Chemistry Question on Enthalpy change
Calculate the standard enthalpy of formation of CH3OH(l) from the following data.
CH3OH(l)+23O2(g)→CO2(g)+2H2O(l) ; ∆rHΘ=–726 kJmol–1,
C(graphite)+O2(g)→CO2(g); ∆cHΘ=–393 kJmol–1,
H2(g)+21O2(g)→H2O(l); ∆fHΘ=–286kJmol–1
Answer
The reaction that takes place during the formation of CH3OH(l) can be written as:
C(s)+2H2O(g)+21O2(g)→CH3OH(l) ……… (i)
The reaction (i) can be obtained from the given reactions by following the algebraic calculations as:
Equation (ii) + 2 × equation (iii) – equation (i)
∆fHΘ[CH3OH(l)]=∆cHΘ+2∆fHΘ[H2O(l)]–∆rHΘ
= (–393 kJmol–1)+2(–286 kJmol–1)–(–726 kJmol–1)
= (–393–572+726) kJmol–1
∴ ∆fHθ[CH3OH(l)]=–239 kJmol–1