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Question

Chemistry Question on The solid state

Calculate the number of atoms in 20 gram metal which crystallises to simple cubic structure having unit cell edge length 340 pm. (density of metal = 9.8 gcm–3)

A

4.95 x 1022

B

5.81 x1022

C

5.19 x 1022

D

5.42 x 1022

Answer

5.19 x 1022

Explanation

Solution

Mass of the metal = 20 g
Density of the metal = 9.8 g/cm³
Unit cell edge length (a) = 340 pm = 340 × 10-10 m
Volume of a cubic unit cell = a3
Number of unit cells = mass(density×volume)\frac {mass}{(density × volume) }
Convert the mass to kilograms:
Mass = 20 g = 20 × 10-3 kg
Number of unit cells = (20×103kg(9.8 g/cm3×volume)\frac {(20 × 10^{-3} kg}{(9.8\ g/cm³ × volume) }
Now, we need to calculate the number of atoms per unit cell in a simple cubic structure, which is 1.
Number of atoms = Number of unit cells × Number of atoms per unit cell
Solving the calculations:
Volume = (340 × 10-10 m)3 = 39.304 × 10-27 m³
Number of unit cells = (20×103kg(9.8 g/cm3×39.304×1027m3)\frac {(20 × 10^{-3} kg}{(9.8\ g/cm³ × 39.304 \times 10^{-27} m^3) }
Number of unit cells = 5.194 × 1022
Number of atoms = (5.194 × 1022) × 1
Therefore, the correct option is (C) 5.19 × 1022 atoms.