Question
Chemistry Question on The solid state
Calculate the number of atoms in 20 gram metal which crystallises to simple cubic structure having unit cell edge length 340 pm. (density of metal = 9.8 gcm–3)
4.95 x 1022
5.81 x1022
5.19 x 1022
5.42 x 1022
5.19 x 1022
Solution
Mass of the metal = 20 g
Density of the metal = 9.8 g/cm³
Unit cell edge length (a) = 340 pm = 340 × 10-10 m
Volume of a cubic unit cell = a3
Number of unit cells = (density×volume)mass
Convert the mass to kilograms:
Mass = 20 g = 20 × 10-3 kg
Number of unit cells = (9.8 g/cm3×volume)(20×10−3kg
Now, we need to calculate the number of atoms per unit cell in a simple cubic structure, which is 1.
Number of atoms = Number of unit cells × Number of atoms per unit cell
Solving the calculations:
Volume = (340 × 10-10 m)3 = 39.304 × 10-27 m³
Number of unit cells = (9.8 g/cm3×39.304×10−27m3)(20×10−3kg
Number of unit cells = 5.194 × 1022
Number of atoms = (5.194 × 1022) × 1
Therefore, the correct option is (C) 5.19 × 1022 atoms.