Solveeit Logo

Question

Question: Calculate \(pH\) of \(0.0001\;M\) of \(HN{O_3}\)....

Calculate pHpH of 0.0001  M0.0001\;M of HNO3HN{O_3}.

Explanation

Solution

The compound given in the question is Nitric acid, it is a very strong acid and a very strong oxidizing agent. It is highly corrosive and toxic in nature, if it comes in contact it can burn the skin. It is colourless but with time it turns into yellow colour because of decomposition of nitric acid into oxides of nitrogen and water.

Complete answer:
It contains three Oxygen atoms and one Hydrogen atom and one Nitrogen atom. We will calculate the concentration of Hydrogen ions in the solution because pHpH is the measure of H+{{\text{H}}^ + } ions in the solution. It is calculated by the formula
pH  =  log10[H+]pH\; = \; - {\log _{10}}\left[ {{{\text{H}}^ + }} \right]
Let’s look at the reaction
HNO3    H+  +  NO3HN{O_3}\; \rightleftarrows \;{{\text{H}}^ + }\; + \;N{O_3}^ -
Nitric acid dissociated into Hydrogen ion and Nitrate ion the concentration of both ions is 0.0001  M0.0001\;M so let us calculate the pHpHof the given amount of nitric acid.
pH  =  log10[H+]pH\; = \; - {\log _{10}}\left[ {{{\text{H}}^ + }} \right]
substituting the value of concentration of hydrogen ions in the nitric acid, we get
pH  =  log10  [0.0001]pH\; = \; - {\log _{10}}\;\left[ {0.0001} \right]
simplifying the equation, we get
pH  =  log10  [104]pH\; = \; - {\log _{10}}\;\left[ {{{10}^{ - 4}}} \right]
as we know log1010  =  1{\log _{10}}10\; = \;1 so log10[104]  =  4{\log _{10}}\left[ {{{10}^{ - 4}}} \right]\; = \; - 4
pH  =  (4)pH\; = \; - \left( { - 4} \right)
pH  =  4pH\; = \;4
so, the pHpH of the given amount of nitric acid is four.

Note:
Be careful when doing the calculations of the pHpH as it involves the calculation of log\log . we write in the from of logaB  =  c{\log _a}B\; = \;c where ac  =  B{{\text{a}}^{\text{c}}}\; = \;{\text{B}} pay attention to the log\log part as it is necessary for the calculation of the pHpH of the solution.