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Question

Chemistry Question on Solutions

Calculate hardness of water in terms of CaCO3 {CaCO_3}. Given Ca(HCO3)2 {Ca(HCO3)2} = 0.81 gm, Mg(HCO3)2 {Mg(HCO3)2} = 0.73 gm, Volume of solution = 100 ml

A

102ppm10^2 ppm

B

103ppm10^3 ppm

C

104ppm10^4 ppm

D

105ppm10^5 ppm

Answer

104ppm10^4 ppm

Explanation

Solution

gmeof  CaCO3=gmeof  Ca(HCO3)+gmeof  Mg(HCO3) {gme of \; CaCO3 = gme of \; Ca(HCO3) + gme of \; Mg(HCO3)} mole×n.f=0.81162×2+0.73146×2\text{mole} \times n.f = \frac{0.81}{162}\times2 + \frac{0.73}{146}\times2 mole  of  CaCO3=1200×2+1200×2 \text{mole} \; \text{of} \; CaCO_{3} = \frac{1}{200} \times2 + \frac{1}{200} \times2 moleofCaCO3=1200+1200=2200=1100mole\text{mole} \text{of} CaCO_{3} = \frac{1}{200} + \frac{1}{200} = \frac{2}{200} = \frac{1}{ 100} \text{mole} Hardness =Wt.of  CaCO3  in  gmWt.of  water  in  gm×106= \frac{Wt. \text{of} \; CaCO_{3} \; \text{in} \; gm }{ Wt. of \; \text{water} \; \text{in} \; gm } \times10^{6} =1100×100100×106=104ppm= \frac{\frac{1}{100} \times100}{100} \times10^{6} = 10^{4} ppm