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Question

Chemistry Question on Electrochemistry

Calculate emf of cell at 25?C Cell notation MM0.012+M0.000012+MM\left|M^{2+}_{0.01}\right|\left|M^{2+}_{0.00001}\right|M If value of E is 4 volt (Given RTF\frac{RT}{F} in 10 = 0.06)

A

3.94 Volt

B

4.06 Volt

C

2.03 Volt

D

8.18 Volt

Answer

3.94 Volt

Explanation

Solution

E=E00.0592E=E^{0}-\frac{0.059}{2} log 104102\frac{10^{-4}}{10^{-2}} E=40.03E=4-0.03 log 10210^{-2} \quad \quad \quad 40.06=3.944-0.06=3.94