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Question

Chemistry Question on Electrochemistry

By passing electric current, NaClO3NaClO_3 is converted into NaClO4NaClO_4 according to the following equation NaClO3+H2ONaClO4+H2Na ClO_3 + H_2 O \rightarrow NaClO_4 + H_2 How many moles of NaClO4NaClO_4 will be formed when three Faradays of charge is passed through NaClO3NaClO_3 ?

A

0.750.75

B

1.01.0

C

1.51.5

D

3.03.0

Answer

1.51.5

Explanation

Solution

The correct answer is C:1.51.5
NaClO3(+5)+H2ONaClO4(+7)+H2\underset{(+5)}{NaClO _{3}}+ H _{2} O \to \underset{(+7)}{NaClO _{4}}+ H _{2}
2F charges required for give 2 moles of electrons therefore 3F3F of charge give =32=1.5=\frac{3}{2}=1.5 moles of electrons.
Hence, 1.51.5 moles of NaClO4NaClO _{4} will be formed.