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Question

Chemistry Question on p -Block Elements

Boric acid is an acid because its molecule

A

contains replaceable H+H^{+} ion

B

gives up a proton

C

accepts OHOH^{-} from water releasing proton

D

combines with proton from water molecule

Answer

accepts OHOH^{-} from water releasing proton

Explanation

Solution

Lewis acids are substances whose octet is incomplete and accepts electrons.

Boric acid is a monobasic weak acid. It does not liberate H+H ^{+} ion but accepts electrons from OHOH ^{-} ion i.e., behaves as Lewis acid.

H3PO3+H2OB(OH)4+H+H _{3} PO _{3}+ H _{2} O \rightarrow B ( OH )_{4}^{-}+ H ^{+}

or B(OH)3+2H2O[B(OH)4]+H3O+B ( OH )_{3}+2 H _{2} O \rightarrow\left[ B ( OH )_{4}\right]^{-}+ H _{3} O ^{+}

The structure of H3BO3H _{3} BO _{3} is as shown below, where the octet of boron in H3BO3H _{3} BO _{3} is incomplete.