Question
Question: B(OH)3 + NaOH \(\rightarrow\) Na[B(OH)4] (aq). Then addition of which of the following proceeds the...
B(OH)3 + NaOH → Na[B(OH)4] (aq).
Then addition of which of the following proceeds the reaction in the forward direction.
A
Glecerol
B
Mannitol
C
Catachol
D
Ethanol
Answer
Glecerol
Explanation
Solution
cis-diols form very stable complex with [B(OH)4]–,
Thus removing it from solution
HB(OH)4 + 2 ⇌

+ H+ + 4H2O.