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Question

Chemistry Question on p -Block Elements

Bleaching powder and bleach solution are produced on a large scale and used in several household products. The effectiveness of bleach solution is often measured by iodometry. Bleaching powder contains a salt of an oxoacid as one of its components. The anhydride of that oxoacid is

A

Cl2OCl_2O

B

Cl2O7Cl_2O_7

C

ClO2ClO_2

D

Cl2O6Cl_2O_6

Answer

Cl2OCl_2O

Explanation

Solution

Ca(OCl)Cl(Bleaching powder)Ca+2+OCl+Cl\underset{\text{(Bleaching powder)}}{Ca(OCl)Cl} \to Ca^{+2} + \overset{-}{O}Cl + Cl^- HOCl(oxo acid>[Δ]H++OCl\underset{\text{(oxo acid}}{HOCl} {->[\Delta]} H^+ + OCl^- 2HOCl>[Δ]H2O+Cl2O2HOCl {->[\Delta]} H_2O + Cl_2O Anhydride of oxoacid (HOCl)(HOCl) is Cl2OCl_2O.