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Question

Chemistry Question on p -Block Elements

Best reagent for the conversion of AgNO3AgNO_3 to Ag is

A

HClO4HClO_4

B

H3PO2H_3PO_2

C

HIO4HIO_4

D

I2I_2

Answer

H3PO2H_3PO_2

Explanation

Solution

H3PO2H_3PO_2 is a good reducing agent as it contains two P-H bonds and thus reduces AgNO3AgNO_3 to Ag. 4AgNO3+H3PO2+2H2O4Ag?+H3PO4+4HNO34AgNO_{3 }+ H_{3}PO_{2} + 2H_{2}O \to4Ag ? + H_{3}PO_{4}+ 4HNO_{3}