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Question

Chemistry Question on Amines

Basic strength is maximum for

A

(CH3)2NH(CH_{3})_{2} NH

B

CH3NH2CH_{3}NH_{2}

C

NH3NH_{3}

D

C6H5NH2C_{6}H_{5}NH_{2}

Answer

(CH3)2NH(CH_{3})_{2} NH

Explanation

Solution

Aromatic amines are far less basic than ammonia and aliphatic amines due to conjugation of lone pair of electrons on NN with benzene ring. Aliphatic amines are stronger bases than am m onia due to +I+I effect of alkyl groups.