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Question

Chemistry Question on Chemical bonding and molecular structure

Based on lattice energy and other considerations which one of the following alkali metal chlorides is expected to have the highest melting point ?

A

RbCl

B

KCl

C

NaCl

D

LiCl

Answer

NaCl

Explanation

Solution

As we go down in the group, ionic character increases hence, melting point of halides should increase but NaCl has the highest melting point (800^{\circ}C) due to its high lattice energy.