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Question: At what temperature is the root mean square speed of an atom in an argon gas cylinder equal to the r...

At what temperature is the root mean square speed of an atom in an argon gas cylinder equal to the rms speed of helium gas atom at –20°C ? (Atomic mass of Ar = 39 u and He = 400 u)

A

2.52 × 103 K

B

2.52 × 102 K

C

4.03 × 103 K

D

4.03 × 102 K

Answer

2.52 × 103 K

Explanation

Solution

Let 1 and 2 represent for Argon atom and Helium atom.

rms speed of Argon vrms1=3RT1M1v_{rms_{1}} = \sqrt{\frac{3RT_{1}}{M_{1}}}

rms speed of Helium , Vrms2=3RT2M2V_{rms_{2}} = \sqrt{\frac{3RT_{2}}{M_{2}}}

According to questions,Vrms1=Vrms2V_{rms_{1}} = V_{rms_{2}}

3RT1M1=3RT2M2\therefore\sqrt{\frac{3RT_{1}}{M_{1}}} = \sqrt{\frac{3RT_{2}}{M_{2}}}

T1M1=T2M2\frac{T_{1}}{M_{1}} = \frac{T_{2}}{M_{2}} or T1=T2M2×M1=2534×39.9T_{1} = \frac{T_{2}}{M_{2}} \times M_{1} = \frac{253}{4} \times 39.9

=2.52×103K= 2.52 \times 10^{3}K