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Question

Chemistry Question on Structure of atom

At temperature T, the average kinetic energy of any particle is 32\frac{3}{2} kT. The de Broglie wavelength follows the order :

A

Thermal proton > Visible photon > Thermal electron

B

Thermal proton > Thermal electron > Visible photon

C

Visible photon > Thermal electron > Thermal neutron

D

Visible photon > Thermal neutron > Thermal electron

Answer

Visible photon > Thermal electron > Thermal neutron

Explanation

Solution

Kinetic energy of any particle =32KT=\frac{3}{2}KT

Also K.E.=12mv2K.E.=\frac{1}{2}mv^{2}
12mv2=32KT\frac{1}{2}mv^{2}=\frac{3}{2}KT
v2=3KTm\Rightarrow v^{2}=\frac{3KT}{m}
v=3KTmv=\sqrt{\frac{3KT}{m}}

De-broglie wavelength

=λ=hmv=hm3KTm=\lambda=\frac{h}{mv}=\frac{h}{m\sqrt{\frac{3KT}{m}}}
λ=h3KTmλ1m\lambda=\frac{h}{\sqrt{3KTm}}\,\lambda\,\propto\, \frac{1}{\sqrt{m}}

Mass of electron < mass of neutron λ\lambda(electron) > λ\lambda (neutron)