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Question: At some instant, a radioactive sample having activity \[5\,\mu Ci\] has twice the number of nuclei a...

At some instant, a radioactive sample having activity 5μCi5\,\mu Ci has twice the number of nuclei as another sample S2S_2 which has an activity of 10μCi10\,\mu Ci. The half-lives of S1S_1 and S2S_2 are
A. 20 years and 5 years, respectively
B. 20 years and 10 years, respectively
C. 10 year eachS1{S_1}
D. 5 year each

Explanation

Solution

Use the relation between the activity of the element, decay constant and population of radioactive element at any time t. Also use the relation between the decay constant and half-life of the element. These two equations when combined give the relation between the activity and half-life of a radioactive element.

Formulae used:
The decay rate equation is given by
A=λNA = \lambda N …… (1)
Here, AA is the activity of a radioactive element, NN is the population of the radioactive element at time tt and λ\lambda is the decay constant.
The formula for the decay constant λ\lambda is
λ=0.693T\lambda = \dfrac{{0.693}}{T} …… (2)
Here, TT is the half-life of the radioactive element.

Complete step by step answer:
It is given that there are two samples S1{S_1} and S2{S_2}which have the activities 5μCi5\,\mu Ci and 10μCi10\,\mu Ci respectively.
A1=5μCi{A_1} = 5\,\mu Ci
A2=10μCi{A_2} = 10\,\mu Ci
The number of nuclei at any time for the sample S1{S_1} are twice as that of the sample S2{S_2}.
N1=2N2{N_1} = 2{N_2}
Substitute 0.693t12\dfrac{{0.693}}{{{t_{\dfrac{1}{2}}}}} for λ\lambda in equation (1).
A=0.693t12NA = \dfrac{{0.693}}{{{t_{\dfrac{1}{2}}}}}N
Rewrite the above equation for the activities of the samples S1{S_1} and S2{S_2}.
A1=0.693T1N1{A_1} = \dfrac{{0.693}}{{{T_1}}}{N_1}
A2=0.693T2N2{A_2} = \dfrac{{0.693}}{{{T_2}}}{N_2}
Divide the equation for A1{A_1} by the equation for A2{A_2}.
A1A2=0.693T1N10.693T2N2\dfrac{{{A_1}}}{{{A_2}}} = \dfrac{{\dfrac{{0.693}}{{{T_1}}}{N_1}}}{{\dfrac{{0.693}}{{{T_2}}}{N_2}}}
A1A2=N1T1T2N2\Rightarrow \dfrac{{{A_1}}}{{{A_2}}} = \dfrac{{{N_1}}}{{{T_1}}}\dfrac{{{T_2}}}{{{N_2}}}
Substitute 5μCi5\,\mu Ci for A1{A_1}, 10μCi10\,\mu Ci for A2{A_2} and 2N22{N_2} for N1{N_1} in the above equation.
5μCi10μCi=2N2T1T2N2\Rightarrow \dfrac{{5\,\mu Ci}}{{10\,\mu Ci}} = \dfrac{{2{N_2}}}{{{T_1}}}\dfrac{{{T_2}}}{{{N_2}}}s
T1T2=41\Rightarrow \dfrac{{{T_1}}}{{{T_2}}} = \dfrac{4}{1}
The ratio of the half-lives of the samples S1{S_1} and S2{S_2} are in the ratio 4:14:1.
From the given options, the half-lives of the samples could only be 20 years and 5 years according to the obtained ratio.

So, the correct answer is “Option A”.

Note:
One may also solve the same question by another method using decay rate equation, activity formula and decay constant formula. The decay rate equation gives the relation between the population of the radioactive element at a particular time and the rate of change of this population with time gives the activity of the element. At last we get the relation between the activity of the radioactive element and its half-life.