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Question: At NTP, \(10{\text{L}}\)of \({{\text{H}}_2}{\text{S}}\) gas reacted with \(10{\text{L}}\) of \({\tex...

At NTP, 10L10{\text{L}}of H2S{{\text{H}}_2}{\text{S}} gas reacted with 10L10{\text{L}} of SO2{\text{S}}{{\text{O}}_2} gas. The volume of gas, after the reaction is complete, would be:
A. 5L{\text{5L}}
B. 10L10{\text{L}}
C. 15L15{\text{L}}
D. 20L20{\text{L}}

Explanation

Solution

A chemical compound contains the same elements in exactly the same proportions by mass regardless of the size of the sample or source of the compound. Volume of a gas is usually measured at NTP. At NTP, one mole of any gas occupies a volume of 22.4L22.4{\text{L}}.

Complete step by step answer:
Avogadro’s law states that equal volumes of gases at the same temperature and pressure contain equal numbers of particles. Molar volume of a gas is 22.4L22.4{\text{L}}.
The balanced chemical reaction is given below:
2H2S+SO22H2O + 3S2{{\text{H}}_2}{\text{S}} + {\text{S}}{{\text{O}}_2} \to 2{{\text{H}}_2}{\text{O + 3S}}
Here, 2mol2{\text{mol}} of H2S{{\text{H}}_2}{\text{S}} is reacted with 1mol1{\text{mol}} of SO2{\text{S}}{{\text{O}}_2} producing 2mol2{\text{mol}} of water molecule and 3mol3{\text{mol}} of sulfur. Mole is used to measure the amount of gases. The mass of one mole of any gas is equal to the molecular mass in grams.
i.e. 2mol2{\text{mol}} of H2S{{\text{H}}_2}{\text{S}} has a volume of 2×22.4L2 \times 22.4{\text{L}} at NTP.
i.e. 2mol2{\text{mol}} of H2S{{\text{H}}_2}{\text{S}} has a volume of 44.8L44.8{\text{L}} at NTP.
22.4L22.4{\text{L}} of SO2{\text{S}}{{\text{O}}_2} gas reacts with 44.8L44.8{\text{L}} of H2S{{\text{H}}_2}{\text{S}}.
1L1{\text{L}} of SO2{\text{S}}{{\text{O}}_2}gas reacts with 22.4L44.8L\dfrac{{22.4{\text{L}}}}{{44.8{\text{L}}}} of H2S{{\text{H}}_2}{\text{S}}.
10L10{\text{L}} of SO2{\text{S}}{{\text{O}}_2} reacts with 22.4L44.8L×10L = 5L\dfrac{{22.4{\text{L}}}}{{44.8{\text{L}}}} \times 10{\text{L = 5L}} of H2S{{\text{H}}_2}{\text{S}}.

So, the correct answer is Option A.

Additional Information:
One mole has an Avogadro number of particles in it. Mole is the measure of the amount of particles in matter. Molar mass of a substance is the mass of one mole of the substance. It is numerically equal to the atomic mass or formula mass.

Note:
The volume of a gas varies with temperature and pressure. Thus the molar volume of a gas at STP is 22.4L22.4{\text{L}}. The standard temperature is 273K273{\text{K}} and standard pressure is 1atm1{\text{atm}}. Molar volume of any gas is used as a conversion when calculating quantities of gases in chemical changes.