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Question: At a certain temperature, the r.m.s. velocity for\(O_{2}\)is 400 m/sec. At the same temperature, the...

At a certain temperature, the r.m.s. velocity forO2O_{2}is 400 m/sec. At the same temperature, the r.m.s. velocity for H2H_{2} molecules will be

A

100 m/sec

B

25 m/sec

C

1600 m/sec

D

6400 m/sec

Answer

1600 m/sec

Explanation

Solution

vrms=3RTM=vrms1Mv_{rms} = \sqrt{\frac{3RT}{M}} = v_{rms} \propto \frac{1}{\sqrt{M}} [T=constant]\lbrack\because T = \text{constant}\rbrack

(vrms)O2(vrms)H2=MH2Mo2400(vrms)H2=232=14\Rightarrow \frac{(v_{rms})_{O_{2}}}{(v_{rms})_{H_{2}}} = \sqrt{\frac{M_{H_{2}}}{Mo_{2}}} \Rightarrow \frac{400}{(v_{rms})_{H_{2}}} = \sqrt{\frac{2}{32}} = \frac{1}{4}

(vrms)H2=1600m/s.\Rightarrow (v_{rms})_{H_{2}} = 1600m/s.