Question
Chemistry Question on Thermodynamics
At 25°C,the dissociation constant of a base, BOH, is 1.0 x 10-12. The concentration of hydroxyl ions in 0.01 M aqueous solution of the base would be:
A
1.0 x 10-6 mol L-1
B
1.0 x 10-5 mol L-1
C
1.0 x 10-8 mol L-1
D
1.0 x 10-7 mol L-1
Answer
1.0 x 10-7 mol L-1
Explanation
Solution
BOH ⇌ B+ +OH-
Kb =[BOH][B+][OH−]
∴ 1×10-12 = 0.01 [OH- ]2
(∵ [OH- ]=[B+ ])
∴ [OH- ]2 =10−14
∴ [OH- ] =10−7
M ⇒ 1.0×10-7 mol L-1
Therefore, the correct option is (D): 1.0×10-7 mol L-1