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Question

Chemistry Question on Thermodynamics

At 25°C,the dissociation constant of a base, BOH, is 1.0 x 10-12. The concentration of hydroxyl ions in 0.01 M aqueous solution of the base would be:

A

1.0 x 10-6 mol L-1

B

1.0 x 10-5 mol L-1

C

1.0 x 10-8 mol L-1

D

1.0 x 10-7 mol L-1

Answer

1.0 x 10-7 mol L-1

Explanation

Solution

BOH ⇌ B+ +OH-

Kb =[B+][OH][BOH]\frac{[B^+][OH^-]}{[BOH]}

\therefore 1×10-12 = 0.01 [OH- ]2 ​

(\because [OH- ]=[B+ ])

\therefore [OH- ]2 =10−14

\therefore [OH- ] =10−7

M \Rightarrow 1.0×10-7 mol L-1

Therefore, the correct option is (D): 1.0×10-7 mol L-1