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Question: At \({{200}^{o}}\) C, hydrogen molecule have velocity \[2.4\times {{10}^{5}}cm{{s}^{-1}}\]. The de B...

At 200o{{200}^{o}} C, hydrogen molecule have velocity 2.4×105cms12.4\times {{10}^{5}}cm{{s}^{-1}}. The de Broglie wavelength in this case is approximately:
A.1 AA{}^\circ
B.1000 AA{}^\circ
C.100 AA{}^\circ
D.10 AA{}^\circ

Explanation

Solution

Wavelength that is associated with an object in relation to its momentum and mass is known as de Broglie wavelength. A particles de Broglie wavelength which is shown by the symbol λ is inversely proportional to its force.

Complete answer:
It is said that matter has a dual nature of wave particles. But it is actually a property of a material object that varies in time or space while behaving similar to waves these type of waves are also called matter waves. De Broglie wavelength is given by
λ=hp\lambda =\dfrac{h}{p}
Where h is planck’s constant 6.6×10276.6\times {{10}^{-27}}ergs
p is the linear momentum which is actually given by the product of mass and volume i.e. p=m×vp=m\times v
Hence According to question
λ=hmv\lambda =\dfrac{h}{mv}
v = 2.4×105cms12.4\times {{10}^{5}}cm{{s}^{-1}}
Mass of one molecule of hydrogen = 2Na\dfrac{2}{{{N}_{a}}}; where Na{{N}_{a}}represents the avogadro’s number having value 6.022×10236.022\times {{10}^{23}}.
Mass of hydrogen = 26.022×1023\dfrac{2}{6.022\times {{10}^{23}}}
Now put all the values in
λ=hmv\lambda =\dfrac{h}{mv}
=6.6×1027×6.022×10232×2.4×105=\dfrac{6.6\times {{10}^{-27}}\times 6.022\times {{10}^{23}}}{2\times 2.4\times {{10}^{5}}}
8.27×109cm8.27\times {{10}^{-9}}cm
=0.8×108cm=0.8\times {{10}^{-8}}cm
= 0.8 AA{}^\circ
Thus, we can say that approximately wavelength is equal to 1 AA{}^\circ ;

So option A is correct.

Note:
De Broglie wavelength has another type called thermal de Broglie wavelength which is approximately the average de Broglie wavelength of the gas particles in an ideal gas at the specified temperature.