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Question

Chemistry Question on Equilibrium

Assuming complete ionization, the pH of 0.1 M, HCl is 1. The molarity of H2SO4H_2SO_4 with the same pH is

A

0.1

B

0.2

C

0.05

D

2

Answer

0.05

Explanation

Solution

pHpH of 0.1HCl=10.1 \,HCl= 1 H2SO4<=>H++HSO4H_{2}SO^{-}_{4} {<=>} H^{+}+HSO^{-}_{4} HSO4<=>H++SO42HSO^{-}_{4} {<=>} H^{+}+SO^{2-}_{4} H2SO4\therefore H_{2}SO_{4} ionises to give two H+H^{+} ions 0.05MH2SO4\therefore 0.05\,M\,H_{2}SO_{4} will give 0.1MH+0. 1 \,M\, H^{+} ion \therefore the molarity of H2SO4=0.05H_{2}SO_{4} = 0.05