Question
Question: Assertion:\(pH\) Of pure water is always \(7.\) Reason:Pure water contains equal concentration of...
Assertion:pH Of pure water is always 7.
Reason:Pure water contains equal concentration of hydronium and hydroxyl ions at room temperature.
A. Both Assertion and reason are correct and Reason is the correct explanation for Assertion.
B. Both Assertion and Reason are correct but Reason is not the correct explanation for Assertion.
C. Assertion is correct but reason is incorrect.
D. Assertion is incorrect Reason is correct.
Solution
pH is a measure of how acidic and basic solution is. The range of pH is 0−14 . The neutral solution have pH equal to 7, pH of acidic solution is always less than 7 and pH of basic solution is always greater than 7.
Complete answer: pH of a solution is depend on temperature and concentration of OH− and H+ ions i.e. if we increase the temperature of solution the solution become acidic it lower down its pH less than 7 because rise in temperature of a solution is associated with increased molecular vibrations, on increasing the temperature, the concentration of H+ ion also increases due to a decreased tendency to form hydrogen bonds, as a result pH of a solution decrease. For example pH of pure water is 7 at 25∘C and pH of pure water is less than 7 at 60∘C.
We also know that pH of solution also depend on concentration of OH− and H+ ions i.e. in acidic solution concentration of H+ ions is more than OH− while in basic solution concentration of H+ ions is less than concentration of OH− ions and in neutral solution concentration of H+ and OH− ions are equal.
Hence, on behalf of the above discussion we can say that pH of pure water is always not equal to 7 but pure water contains equal concentration of hydronium and hydroxyl ions at room temperature.
Therefore the given Assertion is incorrect but Reason is correct.
So the correct option is D.
Note: If pH of the solution is less than 7,it is an acidic solution.If pH of solution is more than 7, it is basic in nature.if it is 7,then the solution is neutral ; water is an example of neutral solution.