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Question: Assertion:\(pH\) Of pure water is always \(7.\) Reason:Pure water contains equal concentration of...

Assertion:pHpH Of pure water is always 7.7.
Reason:Pure water contains equal concentration of hydronium and hydroxyl ions at room temperature.
A.A. Both Assertion and reason are correct and Reason is the correct explanation for Assertion.
B.B. Both Assertion and Reason are correct but Reason is not the correct explanation for Assertion.
C.C. Assertion is correct but reason is incorrect.
D.D. Assertion is incorrect Reason is correct.

Explanation

Solution

pHpH is a measure of how acidic and basic solution is. The range of pHpH is 0140 - 14 . The neutral solution have pHpH equal to 77, pHpH of acidic solution is always less than 77 and pHpH of basic solution is always greater than 7.7.

Complete answer: pHpH of a solution is depend on temperature and concentration of OHO{H^ - } and H+{H^ + } ions i.e. if we increase the temperature of solution the solution become acidic it lower down its pHpH less than 77 because rise in temperature of a solution is associated with increased molecular vibrations, on increasing the temperature, the concentration of H+{H^ + } ion also increases due to a decreased tendency to form hydrogen bonds, as a result pHpH of a solution decrease. For example pHpH of pure water is 77 at 25C{25^ \circ }C and pHpH of pure water is less than 77 at 60C.{60^ \circ }C.
We also know that pHpH of solution also depend on concentration of OHO{H^ - } and H+{H^ + } ions i.e. in acidic solution concentration of H+{H^ + } ions is more than OHO{H^ - } while in basic solution concentration of H+{H^ + } ions is less than concentration of OHO{H^ - } ions and in neutral solution concentration of H+{H^ + } and OHO{H^ - } ions are equal.
Hence, on behalf of the above discussion we can say that pHpH of pure water is always not equal to 77 but pure water contains equal concentration of hydronium and hydroxyl ions at room temperature.
Therefore the given Assertion is incorrect but Reason is correct.

So the correct option is D.D.

Note: If pH of the solution is less than 7,it is an acidic solution.If pH of solution is more than 7, it is basic in nature.if it is 7,then the solution is neutral ; water is an example of neutral solution.