Question
Question: Assertion \(C{O_2}\) is non polar while \(S{O_2}\) is polar molecule. Reason \(S - O\) bonds a...
Assertion
CO2 is non polar while SO2 is polar molecule.
Reason
S−O bonds are polar while C−O are non polar.
A.Both assertion and reason are correct and reason is the correct explanation for assertion
B.Both assertion and reason are correct but reason is not the correct explanation for assertion
C.Assertion is correct but reason is incorrect
D.Assertion is incorrect but reason is correct
Solution
Carbon dioxide is a linear molecule while sulfur dioxide is a bent molecule. Both molecules contain polar bonds, but carbon dioxide is a nonpolar molecule while sulfur dioxide is a polar molecule. It contains two polar bonds that are arranged symmetrically. Carbon forms a double bond with each oxygen atom. But the geometry of carbon dioxide is linear so that the two bond dipole moments cancel and there is no net molecular dipole moment.
Complete answer:
CO2 is a linear molecule so the resultant dipole moment is zero since the individual dipole moments of the CO bond cancel each other. Whereas, SO2 is an angular molecule due to which it has a net dipole moment. Hence SO is polar and CO is non- polar. CO2 is a linear molecule and the oxygen atoms on each end are symmetrical . Whereas the SO2 molecule is bent shaped and is polar because of the electronegativity difference between Sulphur and oxygen . Resulting in a net dipole moment . This doesn't occur in CO2 molecule hence its non polarity .
CO is polar in nature because of the difference in electronegativity of carbon and oxygen atoms. The carbon and oxygen atom have unequal charge distribution and therefore
CO bond has a net dipole moment making CO a polar molecule. The S−O bond in SO2 is polar since there is an electronegativity difference between the sulfur and oxygen atoms.
So, the correct answer is (C) Assertion is correct but reason is incorrect.
Note:
To determine the polarity of a covalent bond using numerical means, find the difference between the electronegativity of the atoms; if the result is between 0.40.4 and 1.7, then, generally, the bond is polar covalent. If there are no polar bonds, the molecule is nonpolar.