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Question: As a result of isobaric heating \(\Delta T = 72K\), one mole of a certain ideal gas obtains an amoun...

As a result of isobaric heating ΔT=72K\Delta T = 72K, one mole of a certain ideal gas obtains an amount of heat Q=1.60kJQ = 1.60kJ. If the value of γ\gamma is (10+x)10\dfrac{{(10 + x)}}{{10}}. Find xx.

Explanation

Solution

Given that the process is isobaric, so this means that the pressure is constant. If a gas expands at a constant pressure, then this process is known as isothermal expansion. In an isobaric process work done is proportional to volume and it is reversible.

Complete step by step solution:
Step I: In an isobaric process, the work done is given by
W=P.dVW = \int {P.dV}
W=PΔVW = P\int {\Delta V}

Step II:
But according to ideal gas law,
PΔV=nRΔTP\Delta V = nR\Delta T
W=nRΔTW = nR\Delta T---(ii)
RR is gas constant and its value is 8.3148.314
For one mole of ideal gas, n=1n = 1
Substitute the given values in equation (ii),
W=1×8.314×72W = 1 \times 8.314 \times 72
W=598.60JW = 598.60J
Or W600J=0.6kJW \approx 600J = 0.6kJ

Step III: Now according to the First Law of thermodynamics, the energy can neither be created nor destroyed. It can be converted from one form to another. For first law of thermodynamics,
ΔU=QW\Delta U = Q - W
Where ΔU\Delta U is the change in internal energy of the system
QQ is the energy or heat supplied
WW is the amount of work done

Step IV: Substitute the given values and find the value of internal energy of the system
ΔU=1.60.6\Delta U = 1.6 - 0.6
ΔU=1kJ\Delta U = 1kJ

Step V: In case of isobaric processes, the internal energy of the system is given by
ΔU=ncvΔT\Delta U = n{c_v}\Delta T---(i)
Where cv{c_v} is the heat capacity of the substance
ΔT\Delta T is the change in temperature
And the amount of heat of the system is given by
Q=ncpΔTQ = n{c_p}\Delta T---(ii)

Step VI:
Dividing equation (i) and (ii),
QΔU=ncpΔTncvΔT\dfrac{Q}{{\Delta U}} = \dfrac{{n{c_p}\Delta T}}{{n{c_v}\Delta T}}
QΔU=cpcv\dfrac{Q}{{\Delta U}} = \dfrac{{{c_p}}}{{{c_v}}}----(iii)

Step VII: Specific heat ratio in the isobaric process is given by gamma γ\gamma . Its formula is
γ=cpcv\gamma = \dfrac{{{c_p}}}{{{c_v}}}---(iv)
Comparing (iii) and (iv)
γ=QΔU\gamma = \dfrac{Q}{{\Delta U}}
γ=1.61\gamma = \dfrac{{1.6}}{1}
γ=1.6\gamma = 1.6

So the value of x is γ=1.6.\gamma = 1.6.

Note: It is important to note that in an isobaric process, the volume of the system is allowed to expand or contract. It is to be done in such a way that it neutralises any pressure change. In an isobaric process, work is done and due to transfer of heat, there is change in internal energy.