Question
Question: As a result of isobaric heating \(\Delta T = 72K\), one mole of a certain ideal gas obtains an amoun...
As a result of isobaric heating ΔT=72K, one mole of a certain ideal gas obtains an amount of heat Q=1.60kJ. If the value of γ is 10(10+x). Find x.
Solution
Given that the process is isobaric, so this means that the pressure is constant. If a gas expands at a constant pressure, then this process is known as isothermal expansion. In an isobaric process work done is proportional to volume and it is reversible.
Complete step by step solution:
Step I: In an isobaric process, the work done is given by
W=∫P.dV
W=P∫ΔV
Step II:
But according to ideal gas law,
PΔV=nRΔT
W=nRΔT---(ii)
R is gas constant and its value is 8.314
For one mole of ideal gas, n=1
Substitute the given values in equation (ii),
W=1×8.314×72
W=598.60J
Or W≈600J=0.6kJ
Step III: Now according to the First Law of thermodynamics, the energy can neither be created nor destroyed. It can be converted from one form to another. For first law of thermodynamics,
ΔU=Q−W
Where ΔU is the change in internal energy of the system
Q is the energy or heat supplied
W is the amount of work done
Step IV: Substitute the given values and find the value of internal energy of the system
ΔU=1.6−0.6
ΔU=1kJ
Step V: In case of isobaric processes, the internal energy of the system is given by
ΔU=ncvΔT---(i)
Where cv is the heat capacity of the substance
ΔT is the change in temperature
And the amount of heat of the system is given by
Q=ncpΔT---(ii)
Step VI:
Dividing equation (i) and (ii),
ΔUQ=ncvΔTncpΔT
ΔUQ=cvcp----(iii)
Step VII: Specific heat ratio in the isobaric process is given by gamma γ. Its formula is
γ=cvcp---(iv)
Comparing (iii) and (iv)
γ=ΔUQ
γ=11.6
γ=1.6
So the value of x is γ=1.6.
Note: It is important to note that in an isobaric process, the volume of the system is allowed to expand or contract. It is to be done in such a way that it neutralises any pressure change. In an isobaric process, work is done and due to transfer of heat, there is change in internal energy.