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Question: Arrange the following metals in increasing order of their reducing power. Given: \({E^{o}}_{K^{+}/...

Arrange the following metals in increasing order of their reducing power.

Given:

EoK+/K=2.93V,EoAg+/Ag=+0.80V,EoAl3+/Al{E^{o}}_{K^{+}/K} = - 2.93V,{E^{o}}_{Ag^{+}/Ag} = + 0.80V,{E^{o}}_{Al^{3 +}/Al}

=1.66V,EoAu3+/Au=+1.40V,EoLi+/Li=3.05V= - 1.66V,{E^{o}}_{Au^{3 +}/Au} = + 1.40V,{E^{o}}_{Li^{+}/Li} = - 3.05V

A

Li < K < Al < Ag < Au

B

Au < Ag < Al < K < Li

C

K < Al < Au < Ag < Li

D

Al < Ag < Au < Li < K

Answer

Au < Ag < Al < K < Li

Explanation

Solution

: Lower the electrode potential, better is the reducing power. The electode potential increases in the order of

}{Al^{3 +}/Al,( - 1.66V),}$$ $Ag^{+}/Ag(\_ 0.80V)$ and $Au^{3 +}/Au( + 1.40V).$ Hence, reducing power of metals will be Au, \< Ag \< Al \< K \< Li