Question
Chemistry Question on Alcohols, Phenols and Ethers
Arrange the following compounds in the increasing order of their acidic strength i. m-nitrophenol ii. m-cresol iii. phenol iv. m-chlorophenol
A
iii<ii<i<iv
B
ii<iv<iii<i
C
ii<iii<iv<i
D
ii<iii<i<iv
Answer
ii<iii<iv<i
Explanation
Solution
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m-cresol has an electron releasing group (CH). Hence, it decreases the acidic strength .Both nitro and chloro are having -I-effect. Hence, they show higher acidic strength. But nitro is a stronger -I-group than chloro group. Hence, m-nitro phenol is more acidic than m-chlorophenol. So increasing order of acidic strength is II < III < IV < I.