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Question

Question: Arrange the acids in terms of their strength....

Arrange the acids in terms of their strength.

Explanation

Solution

The acid strength of the halogen acids depends on how stronger the bond is between the halogen acids. Weaker the bond, more easily it will donate protons, more will be the acidic strength.

Complete answer:
Recalling the periodic trends that ionic size increases as we move down the group. Because fluorine is at the top of the halogens, the fluorine ion is a smaller halide; therefore, the HFH - F bond is short. Shorter bonds are more stable, and thus the HFH - F bond is more difficult to break so the hydrogen ion can’t release easily. Chlorine is large and has more electrons, and therefore the HClH - Cl bond is longer and weaker. In presence of water it is easy to break the HClH - Cl bond, and the ions dissociate in solutions.
The same reasoning applied for both HBrHBr and HIHI . These acids are even stronger than HClHCl because the BrB{r^ - } and I{I^ - } ions are even larger. As such, the HBrH - Br and HIH - I bonds are even weaker, and these compounds also readily dissociate in solution.
So, HIHI being bigger in size, has the lowest value of the bond strength and thus, will have the highest acidic character. On the other hand, HFHF being smaller in size, has the highest value of the bond strength and thus, will have the lowest acidic character.
Thus, the order of acidic character is as:
HI>HCl>HBr>HFHI > HCl > HBr > HF .

Note:
Remember, moving down the group decreases the electronegativity because the size of the element increases thus, the atom becomes easy to lose H+{H^ + } ion. This causes the increase in the strength down the group. And the size increases from top to bottom and hence bond decreases and thus, acidic character increases.