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Question

Chemistry Question on reaction mechanism

Arrange in order of increasing acidic strength

A

X > Z > Y

B

Z < X > Y

C

X > Y > Z

D

Z > X > Y

Answer

X > Z > Y

Explanation

Solution

Carboxylic acid is stronger acid than ammonium ion, hence
-COOH(X) is most acidic. Z(NH3)+_{Z(NH_3)}^{ \, \, \, \, \, +} is more acidic than Y(NH3)+_{Y(NH_3)}^{ \, \, \, \, \, +}
due to - / effect of -COOH on Z. Hence, overall acid strength
order is
X > Z > Y