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Question

Chemistry Question on Equilibrium

Aqueous solutions of HNO3KOH,CH3COOHHNO_3 \, KOH, \, CH_3COOH and CH3COONaCH_3COONa of identical concentrations are provided. The pair(s) of solutions which form a buffer upon mixing is(are)

A

HNO3andCH3COOHHNO_3 and CH_3COOH

B

KOHandCH3COONaKOH and CH_3COONa

C

HNO3andCH3COONaHNO_3 and CH_3COONa

D

CH3COOHandCH3COONaCH_3COOH and CH_3COONa

Answer

CH3COOHandCH3COONaCH_3COOH and CH_3COONa

Explanation

Solution

In HNO3andCH3COONaHNO_3 \, and \, CH_3COONa combination, if HNO3HNO_3
is present in limiting amount, it will be neutralised
completely, leaving behind some excess of CH3COONa.CH_3COONa.