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Question

Chemistry Question on p -Block Elements

Aqueous solution of Na2S2O3Na_2S_2O_3 on reaction with Cl2Cl_2 gives

A

Na2S4O6Na_2S_4O_6

B

NaHSO4NaHSO_4

C

NaClNaCl

D

NaOHNaOH

Answer

NaHSO4NaHSO_4

Explanation

Solution

Sodium thiosulphate, Na2S2O3Na_2S_2O_3 gets oxidised by chlorine
water as Na2S2O3+4Cl2+5H2O2NaHSO4+8HClNa_2S2O_3 + 4Cl_2 + 5 H_2O \longrightarrow 2NaHSO_4 + 8HCl
FeCl3oxidisesNa2S2O3toNa2S4O6FeCl_3 oxidises Na_2S_2O_3 to Na_2S_4O_6