Solveeit Logo

Question

Question: Antimony reacts with sulphur according to the equation \[2Sb\left( s \right) + 3S\left( s \right) ...

Antimony reacts with sulphur according to the equation
2Sb(s)+3S(s)Sb2S3(s)2Sb\left( s \right) + 3S\left( s \right) \to S{b_2}{S_3}\left( s \right)
The molar mass of Sb2S3S{b_2}{S_3} is 340gmol1340gmo{l^{ - 1}}. What is the percentage yield for a reaction in which 140g1 \cdot 40g of Sb2S3S{b_2}{S_3} is obtained from 173g1 \cdot 73g of antimony and a slight excess of sulphur??
A.809%80 \cdot 9\%
B.58.0%58.0\%

Explanation

Solution

In the question above yield percentage has to be calculated, the required parameters are the original or actual yield obtained and calculated or predicted yield which is as whole multiplied by 100100 to obtain the percentage.
Formula used: In order to obtain yield percentage, following formula has to be used %yield=Originalcalculated×100\% yield = \dfrac{{Original}}{{calculated}} \times 100

Complete step by step answer:
Before finding the yield percentage, we have to note down the molar masses of the following,
Antimony Sb=12176g/molSb = 121 \cdot 76g/mol
Sulphur S=32g/molS = 32g/mol
Antimony trisulphide Sb2S3=340g/molS{b_2}{S_3} = 340g/mol
Next, we have to moles of SbSb from the given 173g1 \cdot 73g of antimony using which antimony trisulphide is obtained and the molar mass of antimony Sb=121.76g/molSb = 121.76g/mol
173g×(1mol12176)=0014mol1 \cdot 73g \times \left( {\dfrac{{1mol}}{{121 \cdot 76}}} \right) = 0 \cdot 014mol (Sb)\left( {Sb} \right)
Now, using the mole ratio we found earlier, the moles of antimony trisulphide (Sb2S3)\left( {S{b_2}{S_3}} \right)is found,
0014mol(Sb)×(1mol(Sb2S3)2mol(Sb))=0.007mol(Sb2S3)0 \cdot 014mol\left( {Sb} \right) \times \left( {\dfrac{{1mol\left( {S{b_2}{S_3}} \right)}}{{2mol\left( {Sb} \right)}}} \right) = 0.007mol\left( {S{b_2}{S_3}} \right)
Now, the moles of antimony trisulphide should be converted to grams (g)\left( g \right)
0007mol(Sb2S3)×(340g/mol1mol)=238grams0 \cdot 007mol\left( {S{b_2}{S_3}} \right) \times \left( {\dfrac{{340g/mol}}{{1mol}}} \right) = 2 \cdot 38grams
Now, finally calculation the yield percentage,
%yield=(actualpredicted)×100\% yield = \left( {\dfrac{{actual}}{{predicted}}} \right) \times 100
%yield=(142377)×100=58.8%\% yield = \left( {\dfrac{{1 \cdot 4}}{{2 \cdot 377}}} \right) \times 100 = 58.8\%
The correct option for the question is (B).

Additional information: The series of steps are written to obtain the percentage of yield. Each and every steps indicate the importance of the substances, units and other values like molar masses and moles. We need to focus on these points in order to understand and make it easy to obtain the required solution.

Note:
The molar masses of substances are required to be known, most the time it is given as in to make the solution a bit easier. Focusing on key points is important as it is the solution that is done step by step and where every step is important. Even the values that have to be calculated should be looked after, because in most of the cases due to small mistakes in signs and mistakes while writing values will make a huge impact on everything, which in turn make us get variations in the final value. General remainder is that looking into units right after the values play a major role, missing those leads to confusion and due to that there will be reduction of marks.