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Question

Chemistry Question on Chemical Reactions

Anisole is the product obtained from phenol by the reaction known as

A

coupling

B

etherification

C

oxidation

D

esterification

Answer

etherification

Explanation

Solution

In presence of NaOHNaOH or KOHKOH, phenol reacts with alkyl halide and gives phenolic ether (C6H5OR)(C_6H_5OR).
C6H5OH+NaOH\ce>[][H2O]C6H5ONa\ce>[RX][NaX]C6H5ORC_6H_5OH + NaOH \ce{->[{}][{-H_2O}]} C_6H_5O - Na \ce{->[{RX}][{-NaX}]} C_6H_5 - O - R
Vapours of C6H5OHC_6H_5OH and CH3OHCH_3OH , with red hot ThO2ThO_2 (thoria) give anisole (phenolic ether).
C6H5OH+CH3Oh\ce>[ThO2][Δ]C6H5OCH3anisole+H2OC_6H_5OH + CH_3Oh \ce{->[{ThO_2}][{\Delta}]} \underset{\text{anisole}}{C_6H_5OCH_3} + H_2O